Equivalent Concept

IMPORTANT

Equivalent Concept: Overview

This topic covers concepts, such as, Normality, Equivalent Weight, Percentage Availability of Chlorine in Bleaching Powder & Labelling of Oleum etc.

Important Questions on Equivalent Concept

EASY
IMPORTANT

What is the  [OH]  in the final solution prepared by mixing 20.0 mL of 0.050 M HCl with 30.0 mL of 0.10  M Ba(OH)2 ?

EASY
IMPORTANT

The number of moles of KMn O 4 That will be needed to react with one mole of sulphite ion in acidic solution is

MEDIUM
IMPORTANT

What volume of oxygen gas (O2) measured at  0°C and 1 atm, is needed to burn completely 1L of propane gas  (C3H8) measured under the same conditions?

MEDIUM
IMPORTANT

The equivalent weight of   N a 2 S 2 O 3 .5 H 2 OandKBr O 3  In the following reactions would be:

  (i)2 S 2 O 3 2 + I 2 S 4 O 6 2 +2 I (ii)Br O 3 +6 H + +6 e B r +3 H 2 O

MEDIUM
IMPORTANT

The density of copper is  8.94 g ml1.  The number of coulombs needed to plate an area   10cm×10cm  to a thickness  102 cm using CuSO4 solution as electrolyte are:

MEDIUM
IMPORTANT

Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of the metal is

HARD
IMPORTANT

1.1 g CH3CH2nCOOH was burnt in excess of air and the resultant gases CO2+H2O were passed through a solution of NaOH. The resulting solution is divided into two equal parts. One part required 75 m.e. of HCl for neutralisation using phenolphthalein as indicator. The other part required 100 m.e. of HCl using methyl orange as indicator. Find n.

MEDIUM
IMPORTANT

Find out the normality of a solution obtained by mixing 0.45 N KOH and 0.60 N NaOH in the ratio 2:1 by volume.

EASY
IMPORTANT

KMnO4 reacts with H2O2 in an acidic medium. The number of moles of oxygen produced per mole of KMnO4 is;

MEDIUM
IMPORTANT

20 mL solution of 0.1 M ferrous sulphate was completely oxidised using a suitable oxidising agent. What is the number of electrons exchanged?

MEDIUM
IMPORTANT

What are the number of moles of KMnO4 that will be needed to react with one mole of SO32-ion  in acidic solution?

EASY
IMPORTANT

How many equivalents of Mg would have to react in order to liberate 4 NA electrons? Mg-2e-Mg2+

MEDIUM
IMPORTANT

Molten AlCl3 is electrolysed with a current of 0.5 A to produce 27.0 g Al.

How many litres of Cl2 at NTP were produced?(Report the answer in 2 significant numbers)

HARD
IMPORTANT

Upon heating a litre of a N2HCl solution, 2.675 g of hydrogen chloride is lost and the volume of the solution shrinks to 750 mL. Calculate:

The normality of the resultant solution.(Express your answer up to three decimal places)

 

MEDIUM
IMPORTANT

Find the equivalent weight of H3PO4, in the reaction,

Ca(OH)2+H3PO4=CaHPO4+2H2O.

HARD
IMPORTANT

If 2 litres of ammonia at 13 °C and 0.90 atmospheric pressure is neutralised by 134 ml of H2SO4 solution, the normality value of the acid is A.

Report the value of A by multiplying with 100 and rounding off the value to two significant figures

 

HARD
IMPORTANT

How many gram of H2S will react with 63.2 g of KMnO4 to produce K2SO4 and MnO2? Give answer after rounding off to the nearest integer.

MEDIUM
IMPORTANT

A certain amount of metal, whose equivalent weight is 28, displaces 0.7 litre of hydrogen measured at NTP from an acid. Calculate the weight of the metal.

Give your answer to the nearest integer value after multiplying with 4.

MEDIUM
IMPORTANT

In the quantitative estimation of hypo(Na2 S2O3.5H2O) with potassium permanganate in faintly alkaline or neutral medium, the equivalent weight of hypo is ________(round off to the nearest integer)

MEDIUM
IMPORTANT

If 6×10-3 mole of K2Cr2O7 reacts completely with 9×10-3 mole of Xn+ to give XO3- and Cr3+, then, the value of n is